FINAL PROGRAM

INTERNATIONAL SYMPOSIUM ON POLYMER SURFACE CHARACTERIZATION

OCTOBER 9-10, 2000

ROBERT TREAT HOTEL

NEWARK, NJ

The study of polymer surfaces is important from both fundamental and applied points of view. The number of applications dependent on polymer surface properties are legion, and the areas where polymer surfaces are of critical importance and concern range from microelectronics to prosthetics. In the last decade or so, the availability of sophisticated surface analytical techniques, particularly ESCA, has been a boon in enhancing our knowledge of polymer surfaces. The purpose of this symposium is to provide a forum for discussion of various ramifications of the myriad surface analytical techniques now available. Primary focus is on the dissemination of the latest information available and the cross-pollination of ideas. Additionally, this symposium is organized to serve as a venue for the mutual and fruitful interaction among participants for the furthering of scientific, professional and practical interests.



SESSION I Monday Morning October 9, 2000



8:30: - OPENING REMARKS



8:35- 9:05: Surface Analysis of Some Polymer-Based Materials by Means of A Soft X-ray Emission Technique; M. Romand and M. Charbonnier; Laboratoire de Sciences et Ingénierie des Surfaces, Université Claude Bernard - LYON 1, 69622 Villeurbanne Cedex, FRANCE



9:05 - 9:35: XPS Investigation of Metal/Conjugated Polymer Interfaces of Relevance to the Polymer-based Light Emitting Diodes; E.T. Kang, S. Li and K.G. Neoh; Department of Chemical Engineering, National University of Singapore, Kent Ridge, SINGAPORE 119260



9:35 - 10:05: Glass/polymer Adhesion. Surface Analysis of the Debonded Interface; H. Arribart1,2, P. Chartier1, J.M. Berquier1,2, P. Rémy2, P. Naël2, J. Jupille2, G. Ryschenkow2; 1) Saint-Gobain Recherche, 2) Laboratoire CNRS/Saint-Gobain " Surface du Verre et Interfaces " 39, quai Lucien Lefranc. F-93303 Aubervilliers, FRANCE



10:05 - 10:30: COFFEE BREAK



10:30 - 11:00: Novel Use of Neutron Scattering to Probe the Structure and Thermodynamics of Thin Polymer Films; Sanat K. Kumar; Department of Materials Science and Engineering, Pennsylvania State University, University Park, PA 16802



11:00 - 11:30: Surface Characterization of Polymers Modified by keV and MeV Ion Beams; Yeonhee Lee; Advance Analysis Center, Korea Institute of Science and Tech. Seoul 136-791, S. KOREA





11:30 - 12:00: Valence Band X-ray Photoemission as a Probe of Polymers and

Polymer Interfaces; Peter M. A. Sherwood, Department of Chemistry, Kansas State

University, Manhattan, Kansas 66506-3701



12:00 - 1:30: LUNCH



SESSION II Monday Afternoon October 9, 2000



1:30 - 2:00: Crosslink Density Gradients Within Thin Epoxy Films Revealed By Solvent Swelling: A Neutron Reflectivity Study;H. Yim, M. Kent, and W. F. McNamara; Dept. 1832, Sandia National Laboratories, Albuquerque, NM.; R. Ivkov and S. Satija; National Institute of Standards and Technology, Gaithersburg, MD.; J. Majewski; LANCSE, Los Alamos National Laboratories, Los Alamos, NM.



2:00 - 2:30: Nanostructured Organic Thin Film Deposition from Low Energy Polyatomic Ions; Luke Hanley; Department of Chemistry, m/c 111, University of Illinois at Chicago, 845 W. Taylor St., 4500 SES, Chicago, IL 60607-7061



2:30 - 3:00: Cyclic Oligomer Segregation at Metallized Polyethylene Terephtalate Surface; P. Bertrand1, and P.-A. Gollier2; 1) Unité PCPM Université Catholique de Louvain, Place Croix du Sud 1, B1348 Louvain-La-Neuve, BELGIUM; 2) Baxter R&D Europe, Rue du Progrès 7, B1400 Nivelles BELGIUM



3:00 - 3:30: COFFEE BREAK



3:30 - 4:00: Adhesion of Microcantilevers for MEMS Reliability Studies; M. P. de Boer; Sandia National Laboratories, Albuquerque, NM 87185



4:00 - 4:30: Modification of EPDM Rubber Surface for Improved Adhesion to Polyurethane Coating; Provatas (nee Dimopoulos), M. Choudhury, N.R., Ginic-Markovic, M., Matisons, J.G.; Ian Wark Research Institute, University of South Australia, The Levels Campus, Mawson Lakes, S.A., 5095



4:30 - 5:00: The Spreading of Alkyl Ketene Dimers (AKD) in Paper and on Smooth Hydrophilic Substrates; W. Shen and I.H. Parker; Australian Pulp and Paper Institute, Department of Chemical Engineering, Monash University, Clayton, Vic. 3800, AUSTRALIA;

N. Brack and P.J. Pigram; Centre for materials and Surface Science, La Trobe University, Bundoora, Vic. 3083, AUSTRALIA



SESSION III Tuesday Morning, October 10, 2000



8:30 - 9:00: Study of Surface Properties of Polymer Adsorbed on a Solid Surface Using IGC Techniques; Henri Balard1, Marie.Pierre Comard2, Rachel Calvet1 and John Dodds2; 1) lnstitut de Chimie de Surfaces et Interfaces - CNRS , Mulhouse (FRANCE) 2) Ecole Nationale Superieure d'Ingenieurs des Mines d'Albi - Carznaux, Albi (FRANCE)



9:00 - 9:30: Characterization of Surface Modified Aramid Fibers and Tire Cords by Plasma Polymerized Coatings; Wim van Ooij; Tonya Shipp and Shijian Luo; University of Cincinnati, Department of Materials Science & Engineering, PO Box 210012, Cincinnati, OH 45221-0012





9:30 - 10:00: Detailed Investigation of the Outer Surface Chemistry of Polymers Using ISS and SIMS: Practical Applications in Adhesion, Surface Treatment and Coatings; Gene R. Sparrow; Advanced R&D, Inc., P.O. Box 302, Lake Elmo, MN 55042



10:00 - 10:30: COFFEE BREAK



10:30 - 11:00: TOF-SIMS and XPS Characterization of Fatty Acid Esters in Polypropylene; David A. Cole; Evans East, 104 Windsor Center, Suite 101, East Windsor, NJ 08520



11:00 - 11:30: Harmonically Modulated Friction Force Microscopy: an AFM Tool for

Analysis and Modification of Polymer Surfaces; Heinz Sturm; Federal Institute for Materials Research, BAM VI.32, Unter den Eichen 87, D-12205 Berlin, GERMANY



11:30 - 12:00: HREELS and SPM Applied to Polymer Surfaces and Interfaces; N. J. DiNardo1, J. M. Vohs2, Y. Wei3, R. Plank2, K. Lee2, T. Twardowski4, E. Gentile4, D. Brennan1 and A. Fernandez5; 1) Department of Physics, Drexel University; 2) Department of Chemical Engineering, University of Pennsylvania; 3) Department of Chemistry, Drexel University; 4) Department of Materials Engineering, Drexel University; 5) Cognis Corporation



12:00 - 1:30: LUNCH



SESSION IV Tuesday Afternoon, October 10, 2000



1:30 - 2:00: Mass Spectrometry Applications to Combinatorial Chemistry; Jiyun Xu and Nick Winograd; 180 MRI Building, State College, PA 16802



2:00 - 2:30: Nanoscale surface mechanical properties of polymer thin films; K.J. Wahl, S.A. Syed Asif1, and R.J. Colton; Code 6170, Chemistry Division, Naval Research Laboratory, Washington, DC 20375-5342; 1) Materials Science and Engineering, University of Florida, Gainesville, FL 32611



2:30 - 3:00: Interaction of Metal Atoms with Polymer Surfaces: Model Studies Using Organic Surfaces of Self-assembled Monolayers; Christof Wöll; Lehrstuhl für Physikalische Chemie I, Ruhr-Universität Bochum, 44780 Bochum, GERMANY



3:00 - 3:30: Embedding of Noble Metal Nanoclusters into Polymers as a Probe of the Surface Glass Transition; V. Zaporojtchenko, J. Erichsen, T. Strunskus and F. Faupel; Lehrstuhl für Materialverbunde, Technische Fakultät der CAU Kiel, Kaiserstr. 2, 24143 Kiel, GERMANY