FINAL PROGRAM





SECOND INTERNATIONAL SYMPOSIUM ON ADHESION ASPECTS OF POLYMERIC COATINGS

MAY 25-26, 2000

ROBERT TREAT HOTEL

NEWARK, NJ

This symposium is the follow on to the first one which was held under the auspices of the Electrochemical Society in Minneapolis, MN, 1981 and will cover the progress and breakthroughs which have occurred in the interim. Polymeric coatings are used for a number of purposes, e.g., decorative, protective, functional (as dielectrics or insulators). Additionally, a special application of polymeric (organic) coatings is their use as lithographic materials for making integrated circuit elements. Irrespective of the purpose of the coating it must adhere well to the underlying substrate. The primary purpose of this Symposium is to bring out the various material/process parameters which influence the adhesion of polymeric coatings with a primary thrust on polymeric coatings which are organic in nature. All kinds of polymeric coatings (including primers and paints) irrespective of thickness (thin, thick, or bulk) and method of deposition (plasma, solution, vapor,... etc.) on a variety of substrates (metals, oxides, glass, polymers) are considered.



SESSION I: Thursday, May 25, 2000



8:30-8:35: OPENING REMARKS



8:35-9:10: Interphase: Formation, Characterization and Relevance to Adherence; Alain A. Roche; INSA de Lyon, Laboratoire des Matériaux, Macromoléculaires (CNRS, UMR 5627), 20 Ave., Albert Einstein, F-69621, Villeurbanne Cedex, FRANCE



9:10-9:40: Dependence of Coating Adhesion on Formulation Variables; J. Baghdachi; Coatings Research Institute, Eastern Michigan University, 430 Forest Ave, Ypsilanti, MI 48197



9:40-10:10: Polymer Composition, Interfacial Chemistry and Adhesion in Multilayered Systems; Ann M. Straccia, Larry P. Haack and Joseph W. Holubka; Ford Research Laboratory, MD 3135, P.O. Box 2053, Dearborn, MI 48121-2053



10:10-10-40: COFFEE BREAK



10:40-11:10: Depletion, a Key Factor in Polymer Adhesion; G. Frens; Delft University of Technology, Laboratory of Physical Chemistry, Julianalaan 136, 2628 BL Delft, THE NETHERLANDS



11:10-11:40: Coating Adhesion Improvements with Soy Phosphate Ester Polyol; Zhong Bin, Chirag Shah, Marufur Rahim, and John Massingill; Coatings Research Institute, Eastern Michigan University, 430 West Forest Avenue, Ypsilanti, MI 48197



11:40-12:10: Adhesion of an Alkyd Paint on Cold Rolled Steel Sheet: Effect of Steel Surface Composition; S. Maeda; Parker Industries, Inc., 2-11-14-12 Nakaikegami, Ohta-ku, Tokyo 146-0081, JAPAN



12:10-1:30: LUNCH







SESSION II: Thursday, May 25, 2000





1:30-2:00: Attaining Adhesion/Cohesion Within Painted Plastics; Rose A. Ryntz; Visteon Automotive Systems, A Subsidiary of Ford Motor Company, 401 Southfield Road, Dearborn, MI 48121



2:00-2:30: Modification of Polymer-Metal Interfaces by Functional and Non-functional Silanes; Wim van Ooij, Danqing Zhu and Senthil K. Jayaseelan; Dept. of Materials Science and Engr., University of Cincinnati, Cincinnati, OH 45221-0012



2:30-3:00: Assessing the Adhesion of Siloxane Polymers on E-glass Fibers Investigated by X-ray Photoelectron Spectroscopy; Leanne Britcher, David Kehoe and Janis G. Matisons; Ian Wark Research Institute, Univ. of South Australia, The Levels SA 5095, AUSTRALIA



3:00-3:30: COFFEE BREAK



3:30-4:00: The Residue (Smut) Formed on Aluminum Alloys During Hydrofluoric Acid Etching and its Effect on a Coating Process; Anurag P. S. Tihaiya and James P. Bell; Institute of Material Science, University of Connecticut, 97 N. Eagleville Road, Storrs, CT 06269-3136



Guy D. Davis; DACCO SCI Inc., 10260 Old Columbia Rd, Columbia, MD 21046



Thomas R. Hanlon; United Technologies Research Center, 411 Silver Lane, MS 129-70, East Hartford, CT 06108



4:00-4:30: Use of the Modified Edge Liftoff Test for Measuring the Adhesion of Multilayer, Thin-Film Microelectronic Structures; Edward O. Shaffer II; The Dow Chemical Company, 1702 Building, Midland, MI 48674



4:30-4:50: Modified Scotch Tape Test: Measurement of Adhesion of a Low Dielectric Constant Organic Polymer on Various Insulator Films; Luona L. N. Goh1,2, Simon Y.M. Chooi1, Yi Xu1, Mei-Sheng Zhou1, S. L. Toh2 and T. E. Tay 2



1) Advanced Technology, Chartered Semiconductor Manufacturing,

60 Woodlands Industrial Park D Street 2, Singapore 738406, SINGAPORE



2) Department of Mechanical Engineering, National University of Singapore,

10 Kent Ridge Crescent, Singapore 119260, SINGAPORE



4:50-5:20: Adhesion of Polymer Protective Coatings on Optical Fibres; Jan Rayss; Lab. of Optical Fibers Technology, Maria Curie Sklodowska University, 20-031 Lublin, POLAND



SESSION III: Friday, May 26, 2000



8:30-9:00: The Role of Fluorine in Modifying Polymer Surfaces by Gas and Plasma Pretreatments; J. F. Friedrich, P. Krüger, G. Kühn, U. Schulz, J. Erdmann1, M. Möller1, A. Lippitz and W. E. S. Unger; Bundesanstalt für Materialforschung und -prüfung (BAM), Unter den Eichen 87, 12200 Berlin, GERMANY

1) Fluor Technik System GmbH Lauterbach, Alte Bergstraße 25-27, 36341 Lauterbach, GERMANY



9:00-9:30: Measurement of Internal Stresses in Polymeric Materials Using Time Resolved Fluorescence; Taiji Ikawa and Tohr Shiga; Toyota Central Research & Development Laboratories Inc., Nagakute-cho, Aichi-gun 480-1192, JAPAN



9:30-10:00: The Scanning Kelvinprobe - a New Technique to Study the Stability of Metal/Polymer Bonds; Michael Rohwerder; Max-Planck-Institut für Eisenforschung, P.O. Box 140444, D-40237 Düsseldorf, GERMANY



10:00-10:30: COFFEE BREAK



10:30-11:00: Study of Different Paint Coatings as Anticorrosive Protection of Several Metals of Industrial Interest in the Canary Islands (Spain); J.J. Santana Rodríguez, F.J. Santana Hernández, and J.E. González González ;Dpto. Ingeniería de Procesos, Universidad de Las Palmas de Gran Canaria, Campus Universitario de Tafira, C.P. 35017, Islas Canarias, SPAIN



11:00-11:30: Scanning Electric Potential (SEPM) and Electric Force (EFM) Imaging of Polymer Surfaces; Fernando Galembeck and Elizabeth F. de Souza; Institute of Chemistry, University of Campinas, P.O. Box 6154, 13083 -970 Campinas(SP), BRAZIL



11:30-12:00: Characterization and Adhesion of Plasma Deposited Films on

Polyester; N.V.Bhat and RR.Deshmukh; Physics Division, Department of Chemical Technology, Matunga,Bombay 400019, INDIA





12:00-1:30: LUNCH





SESSION IV: Friday, May 26, 2000





1:30-2:00: Effect of Electrochemical Process Variables on the Adhesion of Polypyrrole Coatings onto Low Carbon Steel, Jude O. Iroh; Department of Materials Science and Engineering, University of Cincinnati, Cincinnati, OH 45221-0012



2:00-2:30: Metal Surface Conditioning Concepts for Resin Bonding in Dentistry; P. Pfeiffer1, Ibrahim Nergiz2 and Mutlu Oezcan3



1) Zentrum für Zahn-, Mund- und Kieferheilkunde der Universitaet zu Koeln,

Kerpener Str. 32, 50931 Koeln GERMANY

2) Abt. f. Zahnerhaltungskunde und Parodontologie der Universitaet Hamburg,

GERMANY

3) University of Marmara, Istanbul, TURKEY



2:30-2:50: Analysis of the Wet Adhesion of Coatings on Wood; Mari de Meijer; SHR Timber Research, P.O.Box 497, 6700 AL Wageningen, THE NETHERLANDS



2:50-3:10: Adhesion Strength of Perfluoronated Dielectric Gel to Polyphenylene Sulfide (PPS); Ying Wang; Motorola, Inc., 4000 Commercial Ave., Northbrook, IL 60062